What is provable and what is valid as a theory is a matter the philosophy of science. This however is common understanding that if there wouldn't be any exceptions if there weren't any rules, without rules anything would be possible and all possibilities valid. There therefore are no rules without their exceptions, as any rule without exception would be absolute. And are there any absolute rule? Only natural laws are absolute.
All rules, by their very definition, as made by man, are exceptional, and nothing made by man is made perfect, is the only rule absolute ... as if man were capable of perfection there wouldn't be any need for rules; everything then would become perfect, without exception. So, rules are there as there are exceptions; and there are no rules without exceptions, aside natural laws.
If you then toss a coin it will fall to the ground, hundred percent, as according to the law of gravity, and then it will settle on to the one of its sides whereby its centre of gravity is closest to its point contact with the ground of its rest, as this is natural rule that all things settle in their optimum state of balance.
The resting of coin on its edge is a possibility of its happening only in the mind, however remote it might in the mind it is there, as given the right natural conditions, a coin will settle of it edge if this is the best position for it to settle – as it happens when you role a coin, or when it rolls down a slot-machine.