This seems like an invitation to speculate about just what your vague question means, while sipping latte's and congratulating each other over how smart we sound.
It recalls the trumped up word games of 18th and 19th century european philosophy that tried to encode everything into a few convenient words; but unlike that philosophy it doesn't even begin to try to explain just what you mean by them.
Since you have left the interpretation of the words entirely open-ended, I'll just assume they mean what I think they mean, then.
Some people in prisons can write books and do what they want to in prisons. They haven't been liberated. But they are real. They also are able to realize their goals.
On the other hand a homeless person who is completely liberated from all responsibility is also almost completely unable to realize any of their goals. Although they are still entirely real, and the most real of their goals are always on their minds, namely food, survive the cold, shelter, maybe beer.
As for what "liberation" and "realization" are, they are words, not concepts. While they can represent concepts, they don't represent any concept at all unless they are given plenty of context. Like, pages and pages of just what you mean by the words. Cause they have lots of different usages, both of them.